Pyridine-2-thiolate bridged tin–palladium complexes with Sn(PdN2Cl2), Sn(PdN2S2), Sn(PdN2C2) and Sn(Pd2N4) skeletons

Erik Wächtler; Robert Gericke; Lyuben Zhechkov; Thomas Heine; Thorsten Langer; Birgit Gerke; Rainer Pöttgen; Jörg Wagler

doi:10.1039/C3CC47912A

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Pyridine-2-thiolate bridged tin–palladium complexes with Sn(PdN₂Cl₂), Sn(PdN₂S₂), Sn(PdN₂C₂) and Sn(Pd₂N₄) skeletons†‡

Erik Wächtler,^a Robert Gericke,^a Lyuben Zhechkov,^b Thomas Heine,^b Thorsten Langer,^c Birgit Gerke,^c Rainer Pöttgen^c and Jörg Wagler*^a

Author affiliations

* Corresponding authors

^a Institut für Anorganische Chemie, TU Bergakademie Freiberg, D-09596 Freiberg, Germany
E-mail: joerg.wagler@chemie.tu-freiberg.de
Fax: +49 3731 39 4058

^b School of Engineering and Science, Theoretical Physics – Theoretical Materials Science, Jacobs University Bremen gGmbH, D-28759 Bremen, Germany

^c Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, D-48149 Münster, Germany

Abstract

Reactions of tin(IV) complexes of the type Sn(PyS)₂X₂ (X = Cl, PyS, Ph; PyS = pyridine-2-thiolate) with Pd(PPh₃)₄ provide easy access to novel heterometallic complexes with Pd–Sn bonds. Electronic characteristics of this connection were analysed by X-ray crystallography, ¹¹⁹Sn Mössbauer spectroscopy and quantum chemical analyses.

This article is part of the themed collection: 2014 Emerging Investigators

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Article information

DOI: https://doi.org/10.1039/C3CC47912A
Article type: Communication
Submitted: 16 okt 2013
Accepted: 02 dec 2013
First published: 03 dec 2013

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Chem. Commun., 2014,50, 5382-5384

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Pyridine-2-thiolate bridged tin–palladium complexes with Sn(PdN₂Cl₂), Sn(PdN₂S₂), Sn(PdN₂C₂) and Sn(Pd₂N₄) skeletons

E. Wächtler, R. Gericke, L. Zhechkov, T. Heine, T. Langer, B. Gerke, R. Pöttgen and J. Wagler, Chem. Commun., 2014, 50, 5382 DOI: 10.1039/C3CC47912A

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Chemical Communications