Issue 77, 2013
From the journal:

Chemical Communications

Voltammetric and spectroscopic characterization of early intermediates in the Co(ii)–polypyridyl-catalyzed reduction of water†

Wangkheimayum Marjit Singh,a   Mohammad Mirmohades,a   Reuben T. Jane,a   Travis A. White,a   Leif Hammarström,a   Anders Thapper,a   Reiner Lomoth*a  and  Sascha Ott*a  

* Corresponding authors

a Department of Chemistry, Ångström Laboratory, Uppsala University, Box 523, 75120 Uppsala, Sweden
E-mail: reiner.lomoth@kemi.uu.se, sascha.ott@kemi.uu.se
Fax: +46 18-471-6844

Abstract

Early intermediates of catalytic water reduction by a Co(II)–polypyridyl species have been characterized. Electrochemical detection of the Co(III)-hydride and time-resolved spectroscopic detection of the Co(I)-ligand intermediates provide an understanding of their reactivity in electrolytic or light-driven reduction of protons to hydrogen.

Graphical abstract: Voltammetric and spectroscopic characterization of early intermediates in the Co(ii)–polypyridyl-catalyzed reduction of water

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC44655G
Article type
Communication
Submitted
21 jun 2013
Accepted
17 jul 2013
First published
22 jul 2013

Chem. Commun., 2013,49, 8638-8640

Permissions

Request permissions

Voltammetric and spectroscopic characterization of early intermediates in the Co(II)–polypyridyl-catalyzed reduction of water

W. M. Singh, M. Mirmohades, R. T. Jane, T. A. White, L. Hammarström, A. Thapper, R. Lomoth and S. Ott, Chem. Commun., 2013, 49, 8638 DOI: 10.1039/C3CC44655G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements