Issue 49, 2013
From the journal:

Chemical Communications

Dioxygen mediated conversion of {Fe(NO)2}9 dinitrosyl iron complexes to Roussin's red esters†

Jessica Fitzpatrick,a   Harris Kalyvas,a   Jason Shearerb  and  Eunsuk Kim*a  

* Corresponding authors

a Department of Chemistry, Brown University, Providence, RI 02912, USA
E-mail: eunsuk_kim@brown.edu
Fax: +1 401-863-9046
Tel: +1 401-863-3591

b Department of Chemistry, University of Nevada, Reno, NV 89557, USA

Abstract

The reactivity of a series of {Fe(NO)2}9 dinitrosyl iron complexes bearing thiolate ligands with molecular oxygen is reported. These reactions result in the formation of the corresponding Roussin's red esters along with thiolate oxidation. This reactivity is contrasted with that previously reported for {Fe(NO)2}10 complexes.

Graphical abstract: Dioxygen mediated conversion of {Fe(NO)2}9 dinitrosyl iron complexes to Roussin's red esters

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Article information

DOI
https://doi.org/10.1039/C3CC40352A
Article type
Communication
Submitted
15 jan 2013
Accepted
24 apr 2013
First published
25 apr 2013

Chem. Commun., 2013,49, 5550-5552

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Dioxygen mediated conversion of {Fe(NO)2}9 dinitrosyl iron complexes to Roussin's red esters

J. Fitzpatrick, H. Kalyvas, J. Shearer and E. Kim, Chem. Commun., 2013, 49, 5550 DOI: 10.1039/C3CC40352A

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