Issue 83, 2012
From the journal:

Chemical Communications

Stepwise construction of grid-type Cu(ii)–Cd(ii) heterometallic MOFs based on an imidazole-appended dipyrrin ligand†‡

Antoine Béziau,a   Stéphane A. Baudron,*a   Dmitry Pogozhev,a   Audrey Flucka  and  Mir Wais Hosseini*a  

* Corresponding authors

a Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université de Strasbourg, Strasbourg, France
E-mail: hosseini@unistra.fr, sbaudron@unistra.fr
Fax: +33 368851325
Tel: +33 368851323

Abstract

An imidazole-appended dipyrrin ligand yields, upon coordination to Cu(II) cations, a linear metallatecton that self-assembles with Cd(II) salts to afford 2D grid-type MOFs which, upon parallel stacking, lead to porous crystals offering 1D channels.

Graphical abstract: Stepwise construction of grid-type Cu(ii)–Cd(ii) heterometallic MOFs based on an imidazole-appended dipyrrin ligand

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Article information

DOI
https://doi.org/10.1039/C2CC35543D
Article type
Communication
Submitted
31 jul 2012
Accepted
30 aug 2012
First published
31 aug 2012

Chem. Commun., 2012,48, 10313-10315

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Stepwise construction of grid-type Cu(II)–Cd(II) heterometallic MOFs based on an imidazole-appended dipyrrin ligand

A. Béziau, S. A. Baudron, D. Pogozhev, A. Fluck and M. W. Hosseini, Chem. Commun., 2012, 48, 10313 DOI: 10.1039/C2CC35543D

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