Issue 67, 2012
From the journal:

Chemical Communications

Zr(iv) and Hf(iv) based metal–organic frameworks with reo-topology†‡

Volodymyr Bon,a   Volodymyr Senkovskyy,b   Irena Senkovska*a  and  Stefan Kaskela  

* Corresponding authors

a Department of Inorganic Chemistry, Dresden University of Technology, Bergstr. 66, 01062 Dresden, Germany
E-mail: irena.senkovska@chemie.tu-dresden.de
Fax: +49 351-4633-7287
Tel: +49 351-4633-2564

b Leibniz-Institut für Polymerforschung Dresden e. V., Hohestr. 6, 01069 Dresden, Germany
E-mail: senkovskyy@ipfdd.de
Fax: +49 351-4658-281
Tel: +49 351-4658-272

Abstract

Zr and Hf based MOFs with enhanced pore accessibility for large molecules and good hydrothermal stability were obtained using a bent dithienothiophene dicarboxylate and Zr4+ or Hf4+ source. A modulator (benzoic acid) facilitates formation of an eight-connecting cluster leading to a new framework which adopts reo topology.

Graphical abstract: Zr(iv) and Hf(iv) based metal–organic frameworks with reo-topology

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Article information

DOI
https://doi.org/10.1039/C2CC34246D
Article type
Communication
Submitted
13 jun 2012
Accepted
04 jul 2012
First published
06 jul 2012

Chem. Commun., 2012,48, 8407-8409

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Zr(IV) and Hf(IV) based metal–organic frameworks with reo-topology

V. Bon, V. Senkovskyy, I. Senkovska and S. Kaskel, Chem. Commun., 2012, 48, 8407 DOI: 10.1039/C2CC34246D

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