Issue 58, 2012

Stepwise activation of “non-innocent” Cp* substituents – a Cp* based cascade reaction

Abstract

Reactions of Cp* substituted pentelidene complexes with the primary phosphine Cp*PH2 yield novel polycyclic phosphorus/arsenic and carbon containing cage compounds via cascade-like reactions. These reactions include a sequence of nucleophilic addition reactions, intramolecular hydrophosphination (partially hydroarsination) reactions, retro-Diels–Alder reactions with Cp*H elimination and subsequent [2+4]-cycloadditions.

Graphical abstract: Stepwise activation of “non-innocent” Cp* substituents – a Cp* based cascade reaction

Supplementary files

Article information

Article type
Communication
Submitted
16 apr 2012
Accepted
30 mei 2012
First published
31 mei 2012

Chem. Commun., 2012,48, 7262-7264

Stepwise activation of “non-innocent” Cp* substituents – a Cp* based cascade reaction

M. Stubenhofer, G. Lassandro, G. Balázs, A. Y. Timoshkin and M. Scheer, Chem. Commun., 2012, 48, 7262 DOI: 10.1039/C2CC32690F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements