Pt(II)-bis(quinolinyl) complexes for photocatalytic hydrogen production

Rahat Gupta; Olivier Schott; Arindam Saha; Shriya; Garry S. Hanan; Amlan K. Pal

doi:10.1039/D3CC04332K

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Pt(ii)-bis(quinolinyl) complexes for photocatalytic hydrogen production†

Rahat Gupta,^a Olivier Schott,^b Arindam Saha,

‡^b Shriya,‡^a Garry S. Hanan

^b and Amlan K. Pal

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Indian Institute of Technology Jammu, Nagrota Bypass Road, Jammu and Kashmir – 181221, India
E-mail: amlan.pal@iitjammu.ac.in

^b Département de Chimie, Université de Montréal, Montréal, Québec H3C 3J7, Canada

Abstract

Three Pt(II)-bis(quinolinyl) complexes with varying electron densities were synthesized, structurally characterized and used for photocatalytic hydrogen production under different conditions. All the complexes were found to be active for hydrogen production giving a maximum turnover number (TON) of 1230 surpassing the conventionally used Pt-terpyridyl complexes.

This article is part of the themed collection: 2023 Emerging Investigators

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Article information

DOI: https://doi.org/10.1039/D3CC04332K
Article type: Communication
Submitted: 01 sep 2023
Accepted: 13 dec 2023
First published: 14 dec 2023

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Chem. Commun., 2024,60, 2022-2025

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Pt(II)-bis(quinolinyl) complexes for photocatalytic hydrogen production

R. Gupta, O. Schott, A. Saha, Shriya, G. S. Hanan and A. K. Pal, Chem. Commun., 2024, 60, 2022 DOI: 10.1039/D3CC04332K

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Chemical Communications

Pt(ii)-bis(quinolinyl) complexes for photocatalytic hydrogen production†

Abstract

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Pt(II)-bis(quinolinyl) complexes for photocatalytic hydrogen production

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