Issue 33, 2021

Iridium-catalysed borylation of pyrene – a powerful route to novel optoelectronic materials

Abstract

Pyrene represents one of the most attractive units for building organic optoelectronic materials. Most pyrene derivatives that have been reported are 1,3,6,8-substituted pyrenes, as these positions are active to electrophilic reactions. By utilising Ir-catalysed borylation, which is sterically driven, Marder and co-workers have developed an effective way to synthesise 2-, 4-, 2,7-, and 4,9-substituted pyrenes, and the photophysics of these pyrene derivatives has been investigated. Similar methodology has also been used in the study of perylene and others. This review summarises the Ir-catalysed borylation of pyrene and other aromatic hydrocarbons, as well as their contributions to the development of organic optoelectronics.

Graphical abstract: Iridium-catalysed borylation of pyrene – a powerful route to novel optoelectronic materials

Article information

Article type
Perspective
Submitted
03 feb 2021
Accepted
04 mrt 2021
First published
04 mrt 2021

New J. Chem., 2021,45, 14869-14878

Iridium-catalysed borylation of pyrene – a powerful route to novel optoelectronic materials

Y. Zhang, L. Tan, J. Shi and L. Ji, New J. Chem., 2021, 45, 14869 DOI: 10.1039/D1NJ00538C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements