Issue 79, 2012
From the journal:

Chemical Communications

Non-interpenetrated IRMOF-8: synthesis, activation, and gas sorption†‡

Jeremy I. Feldblyum,ab   Antek G. Wong-Foyb  and  Adam J. Matzger*ab  

* Corresponding authors

a Macromolecular Science and Engineering, University of Michigan, 2300 Hayward Ave., Ann Arbor, Michigan, USA
E-mail: matzger@umich.edu

b Department of Chemistry, University of Michigan, 930 N. University, Ann Arbor, Michigan, USA

Abstract

The synthesis and successful activation of IRMOF-8 (Zn4O(ndc)3, ndc = naphthalene-2,6-dicarboxylate) is presented. Room temperature synthesis effectively suppresses interpenetration. Although conventional activation under reduced pressure leads to structural collapse, activation by flowing supercritical CO2 yields a guest-free material with a BET surface area of 4461 m2 g−1.

Graphical abstract: Non-interpenetrated IRMOF-8: synthesis, activation, and gas sorption

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Article information

DOI
https://doi.org/10.1039/C2CC34689C
Article type
Communication
Submitted
30 jun 2012
Accepted
12 aug 2012
First published
29 aug 2012

Chem. Commun., 2012,48, 9828-9830

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Non-interpenetrated IRMOF-8: synthesis, activation, and gas sorption

J. I. Feldblyum, A. G. Wong-Foy and A. J. Matzger, Chem. Commun., 2012, 48, 9828 DOI: 10.1039/C2CC34689C

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