Issue 21, 2011
From the journal:

Chemical Communications

Two levels of conformational pre-organization consolidate strong CH hydrogen bonds in chloride–triazolophane complexes†‡

Yuran Hua,a   Raghunath O. Ramabhadran,a   Jonathan A. Karty,a   Krishnan Raghavacharia  and  Amar H. Flood*a  

* Corresponding authors

a Department of Chemistry, Indiana University, 800 East Kirkwood Avenue, Bloomington, USA
E-mail: aflood@indiana.edu
Fax: +1 (812)855-8300
Tel: +1 (812)856-3642

Abstract

Structural rigidity is verified as a pre-organizational factor that acts together with the macrocyclic effect such that synthesis helps in paying the cost of bringing together electropositive CH donors ready for H-bonding with chloride.

Graphical abstract: Two levels of conformational pre-organization consolidate strong CH hydrogen bonds in chloride–triazolophane complexes

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Article information

DOI
https://doi.org/10.1039/C1CC10428D
Article type
Communication
Submitted
21 jan 2011
Accepted
03 apr 2011
First published
26 apr 2011

Chem. Commun., 2011,47, 5979-5981

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Two levels of conformational pre-organization consolidate strong CH hydrogen bonds in chloride–triazolophane complexes

Y. Hua, R. O. Ramabhadran, J. A. Karty, K. Raghavachari and A. H. Flood, Chem. Commun., 2011, 47, 5979 DOI: 10.1039/C1CC10428D

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