Issue 24, 2006

A metal–organic framework material that functions as an enantioselective catalyst for olefin epoxidation

Abstract

A new microporous metal–organic framework compound featuring chiral (salen)Mn struts is highly effective as an asymmetric catalyst for olefin epoxidation, yielding enantiomeric excesses that rival those of the free molecular analogue. Framework confinement of the manganese salen entity enhances catalyst stability, imparts substrate size selectivity, and permits catalyst separation and reuse.

Graphical abstract: A metal–organic framework material that functions as an enantioselective catalyst for olefin epoxidation

Supplementary files

Article information

Article type
Communication
Submitted
10 jan 2006
Accepted
09 mei 2006
First published
23 mei 2006

Chem. Commun., 2006, 2563-2565

A metal–organic framework material that functions as an enantioselective catalyst for olefin epoxidation

S. Cho, B. Ma, S. T. Nguyen, J. T. Hupp and T. E. Albrecht-Schmitt, Chem. Commun., 2006, 2563 DOI: 10.1039/B600408C

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