Themed collection Journal of Materials Chemistry A Recent Review Articles

Topological quantum materials in catalysis
Let's quantum: topological quantum materials offer high electron mobility, stable surface states, and resistance to contamination, making them ideal candidates for next-generation heterogeneous catalysts.
J. Mater. Chem. A, 2025,13, 6325-6341
https://doi.org/10.1039/D4TA08325C

Reducibility, Adsorption Energies, Surface Acidity - Fundamental Material Properties for Fast Oxygen Exchange
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA05637C
Disorder by design: high-entropy oxides as next generation thermoelectric materials
Entropy-engineered oxides for thermoelectric energy.
J. Mater. Chem. A, 2025,13, 27050-27068
https://doi.org/10.1039/D5TA02713F
Electrochemical impedance spectroscopy measurements of solid oxide cells: beyond open circuit voltage conditions
This work emphasizes the importance of performing electrochemical impedance spectroscopy analyses in loading mode rather than under open circuit voltage conditions.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04017E
Beyond traditional TOF: unveiling the pitfalls in electrocatalytic active site determination
TOF reflects intrinsic catalytic activity by measuring per-site efficiency, unlike current density. Accurate TOF estimation requires identifying true active sites and RDS, enabling rational design of efficient electrocatalysts for sustainable water splitting.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04810A
Repurposing PVA-based slime to address electrolyte challenges in portable electrochemical devices
PVA-based slime is an unexplored, cost-effective, and spill-proof alternative to conventional electrolytes. Its inherent ionic conductivity makes it a promising electrolyte for portable electrochemical surface-monitoring probes.
J. Mater. Chem. A, 2025,13, 26202-26214
https://doi.org/10.1039/D5TA03449C
Stabilizing ultrafine intermetallics on carbon supports: from structural design to catalytic applications
Ultrafine intermetallics (<5 nm) offer unique catalytic properties but face sintering challenges. We highlight carbon-supported synthesis strategies for precise control, focusing on electrocatalytic applications and future directions.
J. Mater. Chem. A, 2025,13, 26186-26201
https://doi.org/10.1039/D5TA04405G

Tribocatalysis: a successful marriage of triboelectricity and heterogeneous catalysis
We discuss how tribocatalysis utilizes friction-generated charges to drive chemical transformations. The proposed mechanistic understanding, catalyst design, and future research directions are examined.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04021C
Ordered energy conversion systems inspired from the biological world
In addressing the urgent challenges facing the energy industry, this perspective emphasizes the importance of offering efficient, clean and low-carbon ordered energy conversion systems by integrating biology and engineering.
J. Mater. Chem. A, 2025,13, 24416-24434
https://doi.org/10.1039/D5TA03826J

On the use of bioprecursors for sustainable silicon-based anodes for Li-ion batteries
Plants and protists: promising sources for Si-based Li-ion battery anodes.
J. Mater. Chem. A, 2025,13, 21421-21435
https://doi.org/10.1039/D5TA02555A
How common is it to get an OER overpotential that is <250 mV?
This work raises concerns about the unintentional mistakes made by researchers developing OER electrocatalysts by overlooking the fundamentals.
J. Mater. Chem. A, 2025,13, 21436-21452
https://doi.org/10.1039/D5TA00009B
Unveiling the significance of working electrode substrates in electrocatalytic water splitting for sustainable hydrogen energy production
This perspective highlights how electrode substrate choice critically affects electrocatalyst performance in water splitting, guiding researchers to design better catalysts by leveraging each substrate’s unique properties.
J. Mater. Chem. A, 2025,13, 19252-19281
https://doi.org/10.1039/D5TA02980E
Recent advancements in metal–organic frameworks (MOFs) for flexible supercapacitors aimed at wearable technology
Flexible supercapacitors have made significant progress, as they can be integral to the wearable technology field due to their unique ability to allow seamless movement for the wearer.
J. Mater. Chem. A, 2025,13, 19236-19251
https://doi.org/10.1039/D5TA01159K
Advances and industrialization of LiFePO4 cathodes in electric vehicles: challenges, innovations, and future directions
Evolution, research focus, industrialization and recovery techniques of LiFePO4 cathodes are reviewed, highlighting their critical role in meeting energy demands, especially in EVs.
J. Mater. Chem. A, 2025,13, 17271-17283
https://doi.org/10.1039/D5TA00166H
From lab to market: the future of zinc–air batteries powered by MOF/MXene hybrids
Zinc–air batteries (ZABs) stand at the forefront of energy storage technologies. However, challenges like slow kinetics and low rechargeability persist. MOF–MXene hybrids enhance performance, enabling sustainable ZAB technology.
J. Mater. Chem. A, 2025,13, 12855-12890
https://doi.org/10.1039/D5TA01344E
Sulfur element achieves rapid and stable migration of Li+ in oxide cathode materials
Higher energy density can be obtained by increasing the charging cut-off voltage of Ni-rich materials to meet the range requirements of electric vehicles.
J. Mater. Chem. A, 2025,13, 9039-9048
https://doi.org/10.1039/D4TA09238D

Capacity-weighted figures-of-merit for battery transport metrics
Fast-charging materials are necessary for a battery-centric future. Ionic and electronic transport crucially determine performance where their capacity-weighted figures-of-merit account for performance across all states-of-charge.
J. Mater. Chem. A, 2025,13, 6314-6324
https://doi.org/10.1039/D4TA06041E
Recent advances in characterization of rechargeable battery materials via scanning probe microscopy
Scanning probe microscopy can be used to obtain topographical, mechanical, electrical, and electrochemical information on a wide range of materials in a variety of environments, including in situ and operando studies for rechargeable battery systems.
J. Mater. Chem. A, 2025,13, 5561-5581
https://doi.org/10.1039/D4TA05975A
Sorbent-based atmospheric water harvesting: engineering challenges from the process to molecular scale
Atmospheric water harvesting is an emerging technique that can potentially increase water access to water-constrained communities.
J. Mater. Chem. A, 2025,13, 4838-4850
https://doi.org/10.1039/D4TA06883A
Bridging the Lab-to-Fab Gaps: Recent Advances in the Reproducibility of Organic Solar Cells
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA05788D
CO2 Utilization in Energy Storage and Conversion
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA04747A
A review of the design, applications, and mechanisms of electrically assisted reverse osmosis and nanofiltration processes
The application of electricity to RO and NF, through the superimposition of external electric fields (ENF, ERO) or the integration of electrically conductive membranes (ECMs), represents a promising approach to outperform conventional processes.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03831F
Recent advances of photothermal technology in CO2 capture and methanation
Overview of the mechanisms and categories of photothermal materials for photothermal CO2 capture and methanation.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03108G
Recent advances in liquid metals as electrodes, electrolytes and interface stabilizers for lithium batteries and beyond
This review presents the recent advances in liquid metals (LMs) as key electrodes, electrolyte materials, and interface stabilizers for lithium and other batteries. The remaining challenges and future opportunities are also illustrated.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04996B
Exploring modification strategies to enhance energy storage performance of BOPP dielectric films
Various modification strategies for enhancing energy storage performance of BOPP films fall into two categories of pre-stretching and post-stretching treatments.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA05149E

Reasonable active site design for promoting water dissociation and carbon monoxide activation in a low-temperature water-gas shift reaction
This work considers different catalyst design ideas for enhancing the low-temperature WGSR performance based on the combination of two half-reactions, which occur on different active sites with different optimizing strategies.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA02030A
Advances in metal-based photoresist materials for EUV lithography and lithographic mechanisms
With the rapid development of the IC industry, lithography, as a key step in IC manufacturing, is facing challenges in various aspects, such as the light source, photomask and photoresist.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04194E
Engineering crystalline property of polymer solid electrolytes for boosted electrochemical performances: a critical review
Summary of crystalline property engineering of SPEs.
J. Mater. Chem. A, 2025,13, 26880-26898
https://doi.org/10.1039/D5TA04066C
Advances in topological quantum materials for energy conversion
Topological surface states enhances charge transport in solar cell, water splitting and photoelectrochemical cells. They can have a great impact on reducing charge recombination, dye degradation, corrosion and heat losses leading to enhanced PCE.
J. Mater. Chem. A, 2025,13, 26936-26966
https://doi.org/10.1039/D5TA02897C
Hydrate-based H2 storage with porous materials as heterogeneous promoters: state of the art and challenges
A multiscale strategy for porous material-assisted H2 hydrate storage, bridging materials properties and engineering operations.
J. Mater. Chem. A, 2025,13, 27001-27049
https://doi.org/10.1039/D5TA04503G
Recent advances in biohybrid membranes for water treatment: preparation strategies, nano-hybridization, bioinspired functionalization, applications, and sustainability analysis
We present a comprehensive review on the synthesis, nano-hybridization, bioinspiration functionalization, water treatment, and sustainability of biohybrid membranes.
J. Mater. Chem. A, 2025,13, 26967-27000
https://doi.org/10.1039/D5TA04214C
Covalent organic framework-derived functional interphase for improving Zn chemistry in aqueous zinc-ion batteries
This review systematically summarizes the cutting-edge development of covalent organic framework-derived functional interphases for improving Zn chemistry in aqueous zinc-ion batteries.
J. Mater. Chem. A, 2025,13, 26847-26866
https://doi.org/10.1039/D5TA04055H
Triple-junction all-perovskite solar cells: a review
This paper reviews the working principles and key parameters of TJPSCs and presents recent research progress, focuses on how component optimization, interface engineering, and charge transport layer improvements influence efficiency.
J. Mater. Chem. A, 2025,13, 26867-26879
https://doi.org/10.1039/D5TA03389F
Towards longevity in solid oxide electrolysis cells: multi-scale modeling and machine learning for degradation diagnosis and mitigation
The degradation of SOECs is influenced by coupling across multiple scales. It is necessary to consider establishing a full-chain research framework that integrates multiscale numerical simulations with artificial intelligence methods.
J. Mater. Chem. A, 2025,13, 26899-26935
https://doi.org/10.1039/D5TA03711E
Electrolyte challenges and strategies toward better rechargeable magnesium-metal batteries
This review comprehensively summarizes the persistent challenges and progress in electrolyte design for rechargeable magnesium batteries (RMBs), aiming to guide the rational design of efficient electrolytes and advancing the development of RMBs.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04882F

Architecting light for catalysis: emerging frontiers in plasmonic–photonic crystal hybrids for solar energy conversion
This review explores how plasmonic–photonic crystal hybrids enable enhanced solar energy conversion by coupling photonic and plasmonic effects. Key advances in structural design, fabrication, and photocatalytic applications are critically discussed.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04044B
Tuning ZnCdS heterostructures for enhanced photocatalysis: hybrid architectures for sustainable energy and environmental applications
ZnCdS-based photocatalysts offer tunable band gaps and excellent activity, enabling solar-driven hydrogen evolution and pollutant removal. This review highlights their evolution, challenges, and strategies for enhanced photocatalytic performance.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04144A
Recent advances in interface engineering of iron triad metal phosphide electrocatalysts towards enhanced hydrogen evolution reaction performance
This review explores iron triad metal phosphide HER electrocatalysts with interface engineering, covering enhancement mechanisms, interface configurations, and research progress, while highlighting challenges and future directions.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04085J
Photocatalytic Synergies: Mechanisms, Enhancement Strategies, and Applications
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA05414A
A comprehensive review of core/shell nanostructures of lead-halide perovskite quantum dots for improved optoelectronic performance and stability
This review summarizes core/shell strategies to passivate surface defects in lead-halide perovskite quantum dots (Pe-CQDs). Structures are classified by energy band alignment and physical characteristics to enhance performance and stability.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03459K
Recent Advances in the Application of Magnetron Sputtering for Lithium Metal Batteries
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA03766B
Taming Polysulfide Shuttle and Lithium Dendrites in Lithium-Sulfur Batteries via All- / Quasi- Solid-State Electrolytes: Recent Progress and Future Prospects
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA06038A
Recent advances in tin halide perovskite solar cells: a critical review
This review summarizes the state-of-the-art development of Sn-based perovskite solar cells, and the fundamental properties of Sn-based perovskites, advanced strategies, and critical perspectives on the future research directions are discussed.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04568A

Advancing the synthesis strategy and interface modification for efficient perovskite quantum dot solar cells
Perovskite quantum dots (PeQDs), as a promising material for photovoltaics for their unique optoelectronic properties, has seen significant improvement in cell performance by the interplay of advanced synthetic strategies and interface modifications.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03996G

Emerging innovations in polymeric hollow fiber membranes for sustainable natural gas valorization
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA04814A
Hypercrosslinked Polymers (HCPs) for CO₂ Capture and Catalytic Conversion: Synthesis, Functionalization, and Applications
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA04419G
Metal/metal oxide–graphene nanocomposites as cathode catalysts for lithium–oxygen batteries
This review presents the development history of metal/metal oxide–graphene nanocomposites for lithium–oxygen batteries and discusses their electrocatalytic mechanisms, structure-performance relationships, technical hurdles and future opportunities.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03097H
Newly Synthesized 2D Polyaramid: Structure, Properties, and Applications in Energy Storage, Electrocatalysis, and Sensing
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA03830H
AFP-Based Anti-Icing Coatings: Present Challenges and Future Opportunities
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA03663A

High throughput computational and experimental methods for accelerated electrochemical materials discovery
The full integration of sustainable technologies to combat climate change relies on discovering cost-competitive, safe, and durable materials, specifically for electrochemical systems that generate energy, store energy, and produce chemicals.
J. Mater. Chem. A, 2025,13, 26041-26066
https://doi.org/10.1039/D5TA00331H
Recent advances in MBenes for Li/Na-ion batteries: from synthesis to application
This review examines MBenes for their structural versatility and electrochemical performance in Li/Na-ion batteries, while addressing synthesis challenges and outlining future research directions for next-generation energy storage.
J. Mater. Chem. A, 2025,13, 26166-26185
https://doi.org/10.1039/D5TA04141D
Polymers for perovskite solar cells: advances and perspectives
This review summarizes recent advancements of polymers in perovskite solar cells (PSCs), revealing their mechanisms and guiding future developments.
J. Mater. Chem. A, 2025,13, 26067-26109
https://doi.org/10.1039/D5TA02970H
Advances in CO catalytic oxidation on typical metal oxide catalysts: performance, mechanism, and optimization
Review of CO oxidation over CuOx, MnOx, CeOx, CoOx: surface, lattice, vacancies, valence; L–H, MvK, E–R mechanisms; low-T, poisoning, stability issues; defect, facet, synergy, interface tuning; flue gas & air purify.
J. Mater. Chem. A, 2025,13, 26129-26165
https://doi.org/10.1039/D5TA03067F
Integrated photothermal and photocatalytic degradation of micro-/nanoplastics: a mini-review with mechanistic insights and future perspectives
Sources of MNPs and various treatment approaches.
J. Mater. Chem. A, 2025,13, 26110-26128
https://doi.org/10.1039/D5TA03680A
Illumination-Induced Photoluminescence Enhancement in Metal Halide Perovskites: Revisiting Mechanisms and Emerging Perspectives
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA02688A
Research Progress of Heterogeneous Catalysts with Different Dimensional Supports for Catalytic Hydrolysis of Ammonia Borane
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA04124D

Advances, challenges, and perspectives in developing CuInX2 (X = S, Se) nanomaterials for solar energy conversion applications
CuInX2 (where X = S, Se) are among group I–III–VI's most recognized semiconductors in the ternary chalcogenides with unique properties for solar energy converting devices.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA05229G
Innovative Conversion Electrode Materials and Electrolyte Strategies in Aqueous Zinc-S/Se Batteries for Advanced Energy Storage
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA04605J
Polymorphs of VO2 and their MXene-based hybrid materials for energy storage applications
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA04219D
Recent advances in metal-based Janus nanomaterials: syntheses and electrocatalytic applications
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA04223B
Recent Advances in Functional Energy Materials for Microbial Fuel Cells: Progress, Challenges, and Future Perspectives
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA04072H
Recent Advances of Bio-inspired Radiative Cooling Films Design in Sustainable Building Applications
J. Mater. Chem. A, 2025, Accepted Manuscript
https://doi.org/10.1039/D5TA04553C
Thermally insulating radiative coolers: fundamentals, manufacturing, and applications in energy-efficient buildings
This review makes a forward-looking ponder and beneficial discussion on state-of-the-art thermally insulating radiative coolers, aiming to boost their rapid updating and implementation.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03930D
High entropy alloys: a comprehensive review of synthesis, properties, and characterization for electrochemical energy conversion and storage applications
A comprehensive overview of recent developments in catalysis related to HEAs, focusing on critical areas such as the HER, OER, ORR, hydrogen storage, zinc–air batteries, and supercapacitors.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03746H
Direct recycling of degraded Ni-rich cathodes: recent advances in regeneration and upcycling
This review summarizes advances in direct recycling of spent Ni-rich layered oxides. It links the complex degradation to direct regeneration and upcycling strategies for efficient, high-value material recovery.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04248H
Current collector engineering for advanced anode-free alkali metal batteries with liquid electrolyte
This review systematically summarizes current collector engineering strategies for anode-free alkali metal batteries, including materials optimization, crystal orientation regulation, porous structure design, and surface modification strategies.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA03762J
Recent progress in high-entropy intermetallics for advanced catalysis
Recent progress in high-entropy intermetallic nanocatalysts: synthesis and advanced catalytic applications.
J. Mater. Chem. A, 2025, Advance Article
https://doi.org/10.1039/D5TA04394H
Advances in metal–organic framework-based materials for sustainable energy solutions
This review summarizes recent advances in using MOFs and their derivatives for energy storage, focusing on MOF-derived carbon heterostructures and metal compound modifications to enhance performance through material and structural optimization.
J. Mater. Chem. A, 2025,13, 25258-25303
https://doi.org/10.1039/D5TA03212A
Interfacial chemistry of CuBi2O4 in aqueous media: engineering strategies for energy and environmental applications
We conducted a systematic analysis of CuBi2O4's surface and interface interactions, investigated a series of novel solutions for CuBi2O4-related challenges, and summarized some of its key applications.
J. Mater. Chem. A, 2025,13, 25304-25315
https://doi.org/10.1039/D5TA04609B
High-entropy materials for electrocatalytic oxygen reduction reaction
This review highlights the structural diversity and entropy-driven design of high-entropy materials for oxygen reduction, revealing key structure–activity relationships and guiding future electrocatalyst development.
J. Mater. Chem. A, 2025,13, 25195-25212
https://doi.org/10.1039/D5TA03392F
About this collection
This collection contains recent Review-type articles published by Journal of Materials Chemistry A, the home for high impact applications, properties and synthesis of exciting new materials for energy and sustainability.
New articles will be added to this collection as soon as possible after publication.