Issue 6, 2017

A facile approach to ketones via Pd-catalyzed sequential carbonylation of olefins with formic acid

Abstract

An effective palladium-catalyzed sequential carbonylation of olefins with formic acid is described. Ketones and the corresponding α,β-enones can be obtained with up to 90% yield. The reaction process is operationally simple and requires no toxic CO.

Graphical abstract: A facile approach to ketones via Pd-catalyzed sequential carbonylation of olefins with formic acid

Supplementary files

Article information

Article type
Research Article
Submitted
09 feb 2017
Accepted
22 feb 2017
First published
22 feb 2017

Org. Chem. Front., 2017,4, 1074-1078

A facile approach to ketones via Pd-catalyzed sequential carbonylation of olefins with formic acid

W. Chang, J. Dai, J. Li, Y. Shi, W. Ren and Y. Shi, Org. Chem. Front., 2017, 4, 1074 DOI: 10.1039/C7QO00111H

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