Issue 15, 2021

Exploiting coordination geometry to tune the dimensions and processability of metallosupramolecular polymers

Abstract

Achieving precise control over the morphology, dimensions and processability of functional materials is a key but challenging requirement for the fabrication of smart devices. To address this issue, we herein compare the self-assembly behavior of two new Pt(II) complexes that differ in the molecular and coordination geometry through implementation of either a monodentate (pyridine) or bidentate (bipyridine) ligand. The molecular preorganization of the bipyridine-based complex enables effective self-assembly in solution involving Pt⋯Pt interactions, while preserving aggregate solubility. On the other hand, increased steric effects of the linear bispyridine-based complex hinder an effective preorganization leading to poorly solvated aggregates when a critical concentration is exceeded.

Graphical abstract: Exploiting coordination geometry to tune the dimensions and processability of metallosupramolecular polymers

Supplementary files

Article information

Article type
Research Article
Submitted
26 apr 2021
Accepted
06 mei 2021
First published
04 jun 2021
This article is Open Access
Creative Commons BY license

Org. Chem. Front., 2021,8, 4138-4143

Exploiting coordination geometry to tune the dimensions and processability of metallosupramolecular polymers

N. Bäumer, K. K. Kartha, S. Buss, J. P. Palakkal, C. A. Strassert and G. Fernández, Org. Chem. Front., 2021, 8, 4138 DOI: 10.1039/D1QO00644D

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