Issue 1, 2020

Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds

Abstract

Electrochemical and theoretical investigations over triple-quadruple-, quintuple-, and sextuple-decker sandwich-type compounds {[(Pc*)Sm][(Pc*)Cdn(Pc*)n][Sm(Pc*)]} (n = 0–3) elucidate successive π–π interaction-linked extension in the perpendicular direction of the phthalocyanine plane along with increasing the stacked tetrapyrrole number, significantly improving the nonlinear optical properties including effective imaginary third order molecular hyperpolarizability and optical limiting threshold.

Graphical abstract: Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds

Supplementary files

Article information

Article type
Paper
Submitted
27 sep 2019
Accepted
18 dec 2019
First published
02 jan 2020
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2020,10, 317-322

Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds

X. Chen, D. Qi, C. Liu, H. Wang, Z. Xie, T. Chen, S. Chen, T. Tseng and J. Jiang, RSC Adv., 2020, 10, 317 DOI: 10.1039/C9RA07847A

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