Issue 16, 2020

C-Glycosylation enabled by N-(glycosyloxy)acetamides

Abstract

The C-glycosylation of C-nucleophiles including allyltrimethylsilane, silyl enol ethers and phenols with N-(glycosyloxy)acetamides as glycosyl donors has been realized. This protocol provides a convenient and practical route for the synthesis of alkyl C-glycosides and aryl 2-deoxy-β-C-glycosides under mild reaction conditions.

Graphical abstract: C-Glycosylation enabled by N-(glycosyloxy)acetamides

Supplementary files

Article information

Article type
Communication
Submitted
17 mrt 2020
Accepted
30 mrt 2020
First published
31 mrt 2020

Org. Biomol. Chem., 2020,18, 3043-3046

C-Glycosylation enabled by N-(glycosyloxy)acetamides

M. Liu, B. Li, T. Li, X. Wu, M. Liu, D. Xiong and X. Ye, Org. Biomol. Chem., 2020, 18, 3043 DOI: 10.1039/D0OB00561D

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