Issue 6, 2020

Turn-on fluorescence in a pyridine-decorated tetraphenylethylene: the cooperative effect of coordination-driven rigidification and silver ion induced aggregation

Abstract

A tetrapyridine-decorated tetraphenylethene (TPE) ligand 1 was designed, which, upon interacting with silver ions, displayed “turn-on” fluorescence in a dilute solution. The fluorescence enhancement can be attributed to the cooperative effect of restriction of the intramolecular rotation by metal coordination and silver ion induced aggregation. Furthermore, the fluorescence turn-on performance of AIE molecules in a dilute solution leads to tunable fluorescence properties including white-light emission by simply mixing AIE and ACQ molecules together, which might bridge the gap between the AIE and ACQ phenomena for the construction of color-tunable fluorescence systems.

Graphical abstract: Turn-on fluorescence in a pyridine-decorated tetraphenylethylene: the cooperative effect of coordination-driven rigidification and silver ion induced aggregation

Supplementary files

Article information

Article type
Paper
Submitted
10 okt 2019
Accepted
10 jan 2020
First published
10 jan 2020

Dalton Trans., 2020,49, 1883-1890

Turn-on fluorescence in a pyridine-decorated tetraphenylethylene: the cooperative effect of coordination-driven rigidification and silver ion induced aggregation

N. Wang, J. Zhang, X. Xu and S. Feng, Dalton Trans., 2020, 49, 1883 DOI: 10.1039/C9DT03985F

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