Issue 86, 2020

Preliminary chemical reduction for synthesizing a stable porous molecular conductor with neutral metal nodes

Abstract

Preliminary chemical reduction of naphthalenediimide (NDI)-based organic ligands was applied to the synthesis of a porous molecular conductor (PMC) with neutral metal nodes (cobalt(II) acetylacetonate). The obtained semiconductive PMC (PMC-2) was stable due to the neutral metal nodes, providing an advantage over electrochemical reduction.

Graphical abstract: Preliminary chemical reduction for synthesizing a stable porous molecular conductor with neutral metal nodes

Supplementary files

Article information

Article type
Communication
Submitted
18 mei 2020
Accepted
23 sep 2020
First published
23 sep 2020

Chem. Commun., 2020,56, 13109-13112

Preliminary chemical reduction for synthesizing a stable porous molecular conductor with neutral metal nodes

S. Koyama, T. Tanabe, S. Takaishi, M. Yamashita and H. Iguchi, Chem. Commun., 2020, 56, 13109 DOI: 10.1039/D0CC03541F

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