Issue 34, 2018

A nitrogen-rich ligand as a scaffold for slow magnetic relaxation in dysprosium-based 0D and 1D architectures

Abstract

A recently designed nitrogen-rich ligand is successfully applied as a scaffold for lanthanide ions to show that the intricate chemistry of energetic materials can be combined with other fields of research, including that of molecular magnetism. Herein, we report the synthesis of two different types of molecular architectures using a single ligand template, in which the discrete monomer exhibits single-molecule magnet-like behaviour along with two well-isolated modes of magnetic relaxation.

Graphical abstract: A nitrogen-rich ligand as a scaffold for slow magnetic relaxation in dysprosium-based 0D and 1D architectures

Supplementary files

Article information

Article type
Paper
Submitted
12 jan 2018
Accepted
08 feb 2018
First published
08 feb 2018

Dalton Trans., 2018,47, 11782-11787

A nitrogen-rich ligand as a scaffold for slow magnetic relaxation in dysprosium-based 0D and 1D architectures

G. Brunet, E. Sebastiao, T. G. Witkowski, I. Korobkov, B. Gabidullin and M. Murugesu, Dalton Trans., 2018, 47, 11782 DOI: 10.1039/C8DT00146D

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