Issue 4, 2017

Hybrid molecular-inorganic materials: a heterometallic [Ni4Tb] complex grafted on superparamagnetic iron oxide nanoparticles

Abstract

A heterometallic Ni4Tb field-induced SMM has been grafted onto the surface of superparamagnetic iron oxide nanoparticles. The magnetic coupling within the Ni4Tb and between the Ni4Tb and iron oxide nanoparticle has been studied by element specific XMCD measurements. The coupling between Ni and Tb is ferromagnetic and the complex remains intact when grafted onto the iron oxide nanoparticles.

Graphical abstract: Hybrid molecular-inorganic materials: a heterometallic [Ni4Tb] complex grafted on superparamagnetic iron oxide nanoparticles

Supplementary files

Article information

Article type
Research Article
Submitted
31 okt 2016
Accepted
22 dec 2016
First published
10 jan 2017

Inorg. Chem. Front., 2017,4, 595-603

Hybrid molecular-inorganic materials: a heterometallic [Ni4Tb] complex grafted on superparamagnetic iron oxide nanoparticles

L. Rosado Piquer, E. Jiménez Romero, Y. Lan, W. Wernsdorfer, G. Aromí and E. C. Sañudo, Inorg. Chem. Front., 2017, 4, 595 DOI: 10.1039/C6QI00468G

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