Issue 4, 2015

Tertiary α-diarylmethylamines derived from diarylketimines and organomagnesium reagents

Abstract

Organomagnesium reagents enable swift and versatile derivatisation of diarylimines to the corresponding α-substituted diarylmethylamines in excellent yields, through fast and clean reactions. Where it occurs, 1,2-reduction can be circumvented using readily accessible dialkylmagnesium reagents.

Graphical abstract: Tertiary α-diarylmethylamines derived from diarylketimines and organomagnesium reagents

Supplementary files

Article information

Article type
Communication
Submitted
26 aug 2014
Accepted
13 nov 2014
First published
13 nov 2014

Chem. Commun., 2015,51, 703-706

Author version available

Tertiary α-diarylmethylamines derived from diarylketimines and organomagnesium reagents

A. Desmarchelier, P. Ortiz and S. R. Harutyunyan, Chem. Commun., 2015, 51, 703 DOI: 10.1039/C4CC06719C

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