Issue 69, 2014
From the journal:

Chemical Communications

Regioselective synthesis and molecular structure of the first derivative of praseodymium-containing metallofullerenes†

Qin Zhou,a   Hui Li,a   Yongfu Lian,*a   Mitsuaki Suzuki,b   Lipiao Bao,c   Wenting Cai,c   Weiwei Wang,d   Shigeru Nagase,d   Xing Luc  and  Takeshi Akasakab  

* Corresponding authors

a Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China
E-mail: chyflian@hlju.edu.cn
Fax: +86 451 86608576
Tel: +86 451 86608576

b Life Science Center for Tsukuba Advanced Research Alliance, University of Tsukuba & Foundation for Advancement of International Science, Tsukuba, Ibaraki 305-8577, Japan

c State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology (HUST), Wuhan 430074, China

d Fukui Institute for Fundamental Chemistry, Kyoto University, Kyoto 606-8103, Japan

Abstract

Regioselective cycloaddition of adamantylidene carbene to Pr@C2v(9)-C82 affords the first derivative of praseodymium-containing metallofullerenes. Single-crystal X-ray crystallographic data in combination with theoretical studies demonstrate that the addition is dictated by the single metal ion encapsulated inside the fullerene cage.

Graphical abstract: Regioselective synthesis and molecular structure of the first derivative of praseodymium-containing metallofullerenes

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Article information

DOI
https://doi.org/10.1039/C4CC02949F
Article type
Communication
Submitted
21 Apr 2014
Accepted
08 Jul 2014
First published
08 Jul 2014

Chem. Commun., 2014,50, 9876-9878

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Regioselective synthesis and molecular structure of the first derivative of praseodymium-containing metallofullerenes

Q. Zhou, H. Li, Y. Lian, M. Suzuki, L. Bao, W. Cai, W. Wang, S. Nagase, X. Lu and T. Akasaka, Chem. Commun., 2014, 50, 9876 DOI: 10.1039/C4CC02949F

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