Issue 57, 2012

Intermediates in the Rh-catalysed dehydrocoupling of phosphine–borane

Abstract

Active species, product distributions and a suggested catalytic cycle are reported for the dehydrocoupling of the phosphineborane H3B·PtBu2H to give HPtBu2BH2PtBu2BH3 using the [Rh(COD)2][BArF4] pre-catalyst.

Graphical abstract: Intermediates in the Rh-catalysed dehydrocoupling of phosphine–borane

Supplementary files

Article information

Article type
Communication
Submitted
16 apr 2012
Accepted
15 mei 2012
First published
18 mei 2012

Chem. Commun., 2012,48, 7185-7187

Intermediates in the Rh-catalysed dehydrocoupling of phosphine–borane

M. A. Huertos and A. S. Weller, Chem. Commun., 2012, 48, 7185 DOI: 10.1039/C2CC32696E

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