Issue 1, 2010

Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis

Abstract

An efficient, classical resolution of the versatile P-ligand intermediate 6-phospha-2,4,8-trioxa-adamantane (CgPH) is described and the rhodium complex of the optically pure secondary phosphine β-CgPH is an active and moderately selective asymmetric hydrogenation catalyst.

Graphical abstract: Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis

Supplementary files

Article information

Article type
Communication
Submitted
11 aug 2009
Accepted
08 okt 2009
First published
02 nov 2009

Chem. Commun., 2010,46, 100-102

Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis

J. Hopewell, P. Jankowski, C. L. McMullin, A. G. Orpen and P. G. Pringle, Chem. Commun., 2010, 46, 100 DOI: 10.1039/B916359J

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