Issue 5, 2017

5-Azadibenzo[a,g]corannulene

Abstract

5-Azadibenzo[a,g]corannulene, the first azacorannulene with a nitrogen on the rim, has been synthesized in seven steps from 4-bromoisoquinoline. The strained pyridine ring opens thermally to a polycyclic aromatic nitrile and hydrolytically to an amino aldehyde with the same polycyclic aromatic hydrocarbon framework.

Graphical abstract: 5-Azadibenzo[a,g]corannulene

Supplementary files

Article information

Article type
Research Article
Submitted
19 dec 2016
Accepted
09 jan 2017
First published
19 jan 2017

Org. Chem. Front., 2017,4, 688-698

5-Azadibenzo[a,g]corannulene

V. M. Tsefrikas, A. K. Greene and L. T. Scott, Org. Chem. Front., 2017, 4, 688 DOI: 10.1039/C6QO00831C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements