Issue 42, 2011

Simple routes to bulky silyl-substituted acetylideligands and examples of V(iii), Fe(ii), and Mn(ii) complexes

Abstract

Synthesis of substituted phenylacetylide ligands 2,6-bis(trimethylsilyl)phenylacetylene (H1) and 2-(triphenylsilyl)phenylacteylene (H2) is reported. Ligand 1 supports tetrahedral complexes of V(III), Fe(II), and Mn(II) (3–5). Complexes 3–5 are high-spin and redox active.

Graphical abstract: Simple routes to bulky silyl-substituted acetylide ligands and examples of V(iii), Fe(ii), and Mn(ii) complexes

Supplementary files

Article information

Article type
Communication
Submitted
02 aug 2011
Accepted
10 sep 2011
First published
26 sep 2011

Chem. Commun., 2011,47, 11680-11682

Simple routes to bulky silyl-substituted acetylide ligands and examples of V(III), Fe(II), and Mn(II) complexes

G. M. Yee, K. Kowolik, S. Manabe, J. C. Fettinger and L. A. Berben, Chem. Commun., 2011, 47, 11680 DOI: 10.1039/C1CC14758G

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