Issue 11, 2003
From the journal:

Chemical Communications

A novel left-handed double helicate constructed from l-tartrate bridged molybdenum(vi) and gadolinium(iii) atoms†

Chuan-De Wu,a   Can-Zhong Lu,*a   Xiang Lin,a   Ding-Ming Wu,a   Shao-Fang Lu,a   Hong-Hui Zhuanga  and  Jin-Shun Huanga  

* Corresponding authors

a The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: czlu@ms.fjirsm.ac.cn

Abstract

The one-dimensional double helicate, [NH4][Mo2O4Gd(H2O)6(L-C4H2O6)2]·4H2O (1), which was synthesized by the reaction of GdCl3, L-tartaric acid and ammonium molybdate in acidified water solution, is built up by two heft-handed single-helical chains, linked up further by eight-coordinated GdIII pieces in an enantiopure left-handed double helical configuration, of which each helix is formed by L-tartrate bridged six-coordinated MoVI atoms.

Graphical abstract: A novel left-handed double helicate constructed from l-tartrate bridged molybdenum(vi) and gadolinium(iii) atoms

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B301542D
Article type
Communication
Submitted
11 Feb 2003
Accepted
07 Apr 2003
First published
02 May 2003

Chem. Commun., 2003, 1284-1285

Permissions

Request permissions

A novel left-handed double helicate constructed from L-tartrate bridged molybdenum(VI) and gadolinium(III) atoms

C. Wu, C. Lu, X. Lin, D. Wu, S. Lu, H. Zhuang and J. Huang, Chem. Commun., 2003, 1284 DOI: 10.1039/B301542D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements