Issue 79, 2024

A Zr-hydroxamate metal–organic framework with intrinsic chelating sites for postsynthetic Pd metalation and Suzuki–Miyaura catalysis

Abstract

A highly crystalline and robust Zr-hydroxamate metal–organic framework (MOF) was prepared from a pyrazine-based ligand, featuring abundant N,N′ chelating sites. High-degree Pd(II) metalation of the MOF was achieved through straightforward postsynthetic modification, with detailed coordination chemistry elucidated spectroscopically. The Pd-functionalized MOF was then studied as a heterogeneous Suzuki–Miyaura catalyst, through combined experimental/computational methods.

Graphical abstract: A Zr-hydroxamate metal–organic framework with intrinsic chelating sites for postsynthetic Pd metalation and Suzuki–Miyaura catalysis

Supplementary files

Article information

Article type
Communication
Submitted
01 aug 2024
Accepted
06 sep 2024
First published
09 sep 2024

Chem. Commun., 2024,60, 11100-11103

A Zr-hydroxamate metal–organic framework with intrinsic chelating sites for postsynthetic Pd metalation and Suzuki–Miyaura catalysis

Z. Shao, C. Xiong, J. Yang, Z. Mei, L. Xiong, W. Wu and C. Liu, Chem. Commun., 2024, 60, 11100 DOI: 10.1039/D4CC03895A

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