Issue 29, 2017

Systematic study of the impact of MOF densification into tablets on textural and mechanical properties

Abstract

Four different metal–organic framework powders (UiO-66, UiO-66-NH2, UiO-67, and HKUST-1) were shaped into tablets. The effect of the applied pressure on porous properties, mechanical resistance and tablet bulk density is reported. We observe a linear relationship between densification and tensile strength for all four studied MOFs, with the slope being MOF-dependent. We also report conditions for improving significantly the volumetric uptake. Finally, we evaluated our tablets' stability over time in the presence of moisture.

Graphical abstract: Systematic study of the impact of MOF densification into tablets on textural and mechanical properties

Supplementary files

Article information

Article type
Paper
Submitted
17 feb 2017
Accepted
16 mai 2017
First published
16 mai 2017

CrystEngComm, 2017,19, 4211-4218

Systematic study of the impact of MOF densification into tablets on textural and mechanical properties

J. Dhainaut, C. Avci-Camur, J. Troyano, A. Legrand, J. Canivet, I. Imaz, D. Maspoch, H. Reinsch and D. Farrusseng, CrystEngComm, 2017, 19, 4211 DOI: 10.1039/C7CE00338B

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