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An organic FET employing a single crystal of a donor–acceptor system based on coronene tetracarboxylate and a methyl viologen derivative exhibited an impressive mobility of 0.53 cm2 V−1 s−1, operating under 2 V in the ambient atmosphere. Quantum mechanical calculations have provided an insight into the hole-dominant transport in the crystal.

Graphical abstract: A charge transfer single crystal field effect transistor operating at low voltages

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