An electrically conducting 3D coronene-based metal–organic framework

Marina I. Schönherr; Patricia I. Scheurle; Laura Frey; Marta Martínez-Abadía; Markus Döblinger; Andre Mähringer; Dominik Fehn; Lena Gerhards; Irina Santourian; Alfred Schirmacher; Tatjana Quast; Gunther Wittstock; Thomas Bein; Karsten Meyer; Aurelio Mateo-Alonso; Dana D. Medina

doi:10.1039/D3TA07120K

An electrically conducting 3D coronene-based metal–organic framework†

Marina I. Schönherr,

‡^ab Patricia I. Scheurle,

‡^ab Laura Frey,

^ab Marta Martínez-Abadía,

^c Markus Döblinger,

^ab Andre Mähringer,

^ab Dominik Fehn,

^d Lena Gerhards,

^e Irina Santourian,

^f Alfred Schirmacher,

^f Tatjana Quast,

^f Gunther Wittstock,

^e Thomas Bein,

^ab Karsten Meyer,

^d Aurelio Mateo-Alonso

^cg and Dana D. Medina

*^ab

Author affiliations

* Corresponding authors

^a Department of Chemistry, Ludwig-Maximilians-Universität (LMU), Butenandtstr. 11 (E), 81377 Munich, Germany
E-mail: dana.medina@cup.lmu.de

^b Center for NanoScience (CeNS), Schellingstr. 4, 80799 Munich, Germany

^c POLYMAT, University of the Basque Country UPV/EHU, Avenida de Tolosa 72, E-20018 Donostia-San Sebastián, Spain

^d Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Department of Chemistry and Pharmacy, Inorganic Chemistry, Egerlandstraße 1, 91058 Erlangen, Germany

^e School of Mathematics and Science, Institute of Chemistry, Carl von Ossietzky University of Oldenburg, 26111 Oldenburg, Germany

^f Physikalisch-Technische Bundesanstalt Braunschweig und Berlin (PTB), Bundesallee 100, 38116 Braunschweig, Germany

^g Ikerbasque, Basque Foundation for Science, 48009 Bilbao, Spain

Abstract

A novel cubic mesoporous metal–organic framework (MOF), consisting of hexahydroxy-cata-hexabenzocoronene (c-HBC) and Fe^III ions is presented. The highly crystalline and porous MOF features broad optical absorption over the whole visible and near infrared spectral regions. An electrical conductivity of 10⁻⁴ S cm⁻¹ was measured on a pressed pellet.

This article is part of the themed collection: Functional Framework Materials

Journal of Materials Chemistry A

An electrically conducting 3D coronene-based metal–organic framework†

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An electrically conducting 3D coronene-based metal–organic framework

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