Photocatalytic CO2 reduction to CO catalysed by lanthanide complexes

Yingzhe Zhao; Jianling Zhang; Haoxiang Wang; Renjie Zhang; Yunan Teng; Meiling Li; Yi Song; Zhonghao Tan

doi:10.1039/D4CC03175J

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Photocatalytic CO₂ reduction to CO catalysed by lanthanide complexes†

Yingzhe Zhao,^ab Jianling Zhang,

*^ab Haoxiang Wang,^ab Renjie Zhang,^ab Yunan Teng,^ab Meiling Li,^ab Yi Song^ab and Zhonghao Tan^ab

Author affiliations

* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
E-mail: zhangjl@iccas.ac.cn

^b School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Abstract

Here we demonstrate the efficient CO₂ reduction to CO catalysed by lanthanide-based complexes under light irradiation, by which the highest CO evolution rate can reach 78 ± 8 μmol g⁻¹ h⁻¹ in 4 h. This work provides an economic and environmentally friendly route for CO₂ conversion.

This article is part of the themed collection: ChemComm 60th Anniversary Collection

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Article information

DOI: https://doi.org/10.1039/D4CC03175J
Article type: Communication
Submitted: 28 jun 2024
Accepted: 30 sep 2024
First published: 01 okt 2024

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Chem. Commun., 2024,60, 12433-12436

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Photocatalytic CO₂ reduction to CO catalysed by lanthanide complexes

Y. Zhao, J. Zhang, H. Wang, R. Zhang, Y. Teng, M. Li, Y. Song and Z. Tan, Chem. Commun., 2024, 60, 12433 DOI: 10.1039/D4CC03175J

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