Tetraphenylpentalenide organolanthanide complexes

Nicholas J. Katzer; Mandeep Kaur; Asmita Sen; Rupal Nimaiyar; Jochen Autschbach; Polly L. Arnold; Ulrich Hintermair

doi:10.1039/D4CC02570A

Tetraphenylpentalenide organolanthanide complexes†

Nicholas J. Katzer,

‡^ab Mandeep Kaur,

‡^c Asmita Sen,

‡^d Rupal Nimaiyar,^a Jochen Autschbach,

*^d Polly L. Arnold

*^ab and Ulrich Hintermair

*^c

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of California, Berkeley, CA, USA
E-mail: pla@berkeley.edu

^b Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA

^c Department of Chemistry, University of Bath, UK
E-mail: u.hintermair@bath.ac.uk

^d Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260, USA
E-mail: jochena@buffalo.edu

Abstract

The D_2h symmetrical 1,3,4,6-tetraphenylpentalenide is an excellent ligand for the stabilisation of strongly coloured bis(pentalenide) Ln^III sandwich complexes. These easily accessible compounds complement previously reported lanthanide organometallics and provide new opportunities to understand the roles of the f-orbitals in electronic structure and bonding.

This article is part of the themed collections: 2024 Pioneering Investigators and Chemical Communications HOT Articles 2024

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Article information

DOI: https://doi.org/10.1039/D4CC02570A
Article type: Communication
Submitted: 27 mai 2024
Accepted: 08 jul 2024
First published: 12 jul 2024
This article is Open Access

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Chem. Commun., 2024, Advance Article

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Tetraphenylpentalenide organolanthanide complexes

N. J. Katzer, M. Kaur, A. Sen, R. Nimaiyar, J. Autschbach, P. L. Arnold and U. Hintermair, Chem. Commun., 2024, Advance Article , DOI: 10.1039/D4CC02570A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Chemical Communications

Tetraphenylpentalenide organolanthanide complexes†

Abstract

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Tetraphenylpentalenide organolanthanide complexes

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