The common electrostatic features of ethynyl and iodoethynyl hydrogen- and halogen-bond donors, respectively, lead to synthon mimicry which can be employed in synthetic crystal engineering for the construction of identical supramolecular assemblies in the solid-state.
C. B. Aakeröy, D. Welideniya and J. Desper, CrystEngComm, 2017, 19, 11 DOI: 10.1039/C6CE02201D
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