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Abstract | Cited by

The synthesis and characterization of two-coordinate cobalt(II) complexes CoAr′2 (1) and Ar′CoN(SiMe3)2 (2) (Ar′ = C6H3-2,6-(C6H3-2,6-iPr2)2) are reported. The magnetic data for 2 show that it has an unexpectedly high μeff of 5.65 μB whereas the bent complex 1 has a significantly lower moment.

Graphical abstract: Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(ii) complex

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