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The presence and stability of sp hybridized atoms in free carbon nanoparticles was investigated by NEXAFS spectroscopy. The experiments show that a predominant fraction of carbon atoms is found in linear sp-chains and that conversion into sp2 structures proceeds already at low temperature and in the gas phase.

Graphical abstract: sp hybridization in free carbon nanoparticles—presence and stability observed by near edge X-ray absorption fine structure spectroscopy

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