Carborane–arene fused boracyclic analogues of polycyclic aromatic hydrocarbons accessed by intramolecular borylation

Abstract

Arenes are 2D aromatics while dicarbadodecaborane clusters are branded as 3D aromatic molecules. In this work we prepare molecules that feature fused 2D/3D aromatic systems that represent boron-doped analogues of polycyclic aromatic hydrocarbons. The electron withdrawing nature of the ortho-carborane substituent enables swift arene borylation on boron bromide or hydride precursors to furnish five- and six-membered boracycles in conjugation with the arene. The mechanism was modeled by DFT computations implying a concerted transition state and analyzing the photophysical properties revealed high quantum yields in the six-membered systems.