Recent trends in incorporation of CO2 into organosulfur compounds via C–S bond cleavage

Abstract

Desulfurative functionalization of organosulfur compounds to form various carbon–carbon and carbon–heteroatom bonds has become established as a powerful tool in organic chemistry. In this context, desulfurative carboxylation of this class of compounds using carbon dioxide (CO₂) as a sustainable and renewable source of carboxyl has recently been developed as an efficient option for the synthesis of carboxylic acid derivatives. The aim of this Focus Review is to summarize the major progress in this appealing research field with particular emphasis on the mechanistic features of the reactions. Literature has been surveyed until the end of February 2024, according to the data collected using SciFinder and Google Scholar engines.