Issue 39, 2021

Hydrophilic and hydrophobic carboxamide pincers as anion hosts

Abstract

Hydrophobic and hydrophilic, monotopic and ditopic carboxamide pincer hosts containing ethyl, hexyl, 2-hydroxyethyl and 2-hydroxyethyl ethyl ether pendant arms were synthesized. Solubility trends indicated that solubilities in water or hydrocarbon solvents varied depending on the nature of the pendant arms. Binding constants for hydrophilic pincers were larger in general than their hydrophobic analogs. Significant synergistic binding effects for the ditopic hosts were not observed.

Graphical abstract: Hydrophilic and hydrophobic carboxamide pincers as anion hosts

Supplementary files

Article information

Article type
Communication
Submitted
15 ဩ 2021
Accepted
06 စက် 2021
First published
09 စက် 2021

Org. Biomol. Chem., 2021,19, 8516-8520

Author version available

Hydrophilic and hydrophobic carboxamide pincers as anion hosts

J. Lohrman, S. Pramanik, S. Kaur, H. Telikepalli, V. W. Day and K. Bowman-James, Org. Biomol. Chem., 2021, 19, 8516 DOI: 10.1039/D1OB01605A

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