Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds

Xin Chen; Dongdong Qi; Chao Liu; Hailong Wang; Zheng Xie; Tse-Wei Chen; Shen-Ming Chen; Tien-Wen Tseng; Jianzhuang Jiang

doi:10.1039/C9RA07847A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds†

Xin Chen,‡^a Dongdong Qi,‡^a Chao Liu,^a Hailong Wang,*^a Zheng Xie,

^b Tse-Wei Chen,^c Shen-Ming Chen,*^c Tien-Wen Tseng

*^c and Jianzhuang Jiang

*^a

Author affiliations

* Corresponding authors

^a Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, China
E-mail: jianzhuang@ustb.edu.cn

^b Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Science, Beijing 100190, China

^c Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, Taipei 10608, Taiwan

Abstract

Electrochemical and theoretical investigations over triple-quadruple-, quintuple-, and sextuple-decker sandwich-type compounds {[(Pc*)Sm][(Pc*)Cd_n(Pc*)_n][Sm(Pc*)]} (n = 0–3) elucidate successive π–π interaction-linked extension in the perpendicular direction of the phthalocyanine plane along with increasing the stacked tetrapyrrole number, significantly improving the nonlinear optical properties including effective imaginary third order molecular hyperpolarizability and optical limiting threshold.

This article is part of the themed collection: Editors' Collection: Phthalocyanines

Download options Please wait...

Supplementary files

Supplementary information PDF (857K)

Article information

DOI: https://doi.org/10.1039/C9RA07847A
Article type: Paper
Submitted: 27 စက် 2019
Accepted: 18 ဒီ 2019
First published: 02 ဇန် 2020
This article is Open Access

Download Citation

RSC Adv., 2020,10, 317-322

Permissions

Request permissions

Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds

X. Chen, D. Qi, C. Liu, H. Wang, Z. Xie, T. Chen, S. Chen, T. Tseng and J. Jiang, RSC Adv., 2020, 10, 317 DOI: 10.1039/C9RA07847A

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

RSC Advances

Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds

Social activity

Search articles by author

Spotlight

Advertisements