Issue 26, 2019

A look at periodic trends in d-block molecular electrocatalysts for CO2 reduction

Abstract

Electrocatalytic CO2 reduction is of continued interest to sustainable energy research. Mononuclear transition metal complexes from Group 6 to Group 10 with a select subset of ligand frameworks have been demonstrated to be efficient electrochemical CO2 reduction catalysts. Here, we review the known mononuclear complexes from Group 6 to Group 10, examining trends in activity, electronic structure of catalytic intermediates, and product selectivity. The correlation between differences in electronic structure and CO2 reduction activity between these metal centers are discussed.

Graphical abstract: A look at periodic trends in d-block molecular electrocatalysts for CO2 reduction

Article information

Article type
Perspective
Submitted
01 ဖေ 2019
Accepted
09 ဧပြီ 2019
First published
09 ဧပြီ 2019

Dalton Trans., 2019,48, 9454-9468

A look at periodic trends in d-block molecular electrocatalysts for CO2 reduction

C. Jiang, A. W. Nichols and C. W. Machan, Dalton Trans., 2019, 48, 9454 DOI: 10.1039/C9DT00491B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements