Issue 16, 2018

Synthesis, structure and characterization of two solvatochromic metal–organic frameworks for chemical-sensing applications

Abstract

Two isostructural Zr and Hf metal–organic frameworks (PU-1 and PU-2) were constructed from a hitherto unreported anthracene-derived dicarboxylate ligand and inorganic [M6O4(OH)4(CO2)12] (M = Zr4+ or Hf4+) secondary building unit under solvothermal conditions. They crystallized in the cubic Fd[3 with combining macron]m space group with doubly interpenetrated fcu-c topology. PU-1 exhibited an eye-catching color change within different solvents (especially in water) and could be a solvatochromic sensing material for recognition of solvent molecules.

Graphical abstract: Synthesis, structure and characterization of two solvatochromic metal–organic frameworks for chemical-sensing applications

Supplementary files

Article information

Article type
Communication
Submitted
07 ဖေ 2018
Accepted
25 မတ် 2018
First published
26 မတ် 2018

CrystEngComm, 2018,20, 2237-2240

Synthesis, structure and characterization of two solvatochromic metal–organic frameworks for chemical-sensing applications

S. Gao, L. Zhao, L. Han, Z. Zhang and H. Zhao, CrystEngComm, 2018, 20, 2237 DOI: 10.1039/C8CE00204E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements