Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework

Hannes Depauw; Irena Nevjestić; Guangbo Wang; Karen Leus; Freddy Callens; Els De Canck; Klaartje De Buysser; Henk Vrielinck; Pascal Van Der Voort

doi:10.1039/C7TA08103K

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework†

Hannes Depauw,^a Irena Nevjestić,

^b Guangbo Wang,^a Karen Leus,

^a Freddy Callens,

^b Els De Canck,^a Klaartje De Buysser,

^a Henk Vrielinck

^b and Pascal Van Der Voort

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Ghent University, Krijgslaan 281-S3, B-9000 Belgium
E-mail: Pascal.vandervoort@ugent.be
Tel: +32-9-264-4442

^b Department of Solid State Sciences, Ghent University, Krijgslaan 281-S1, B-9000 Belgium

Abstract

A new series of bimetallic COMOC-2(V)/DUT-5(Al) frameworks are developed and fully characterized. Electron paramagnetic resonance and transmission electron microscopy confirm the homogeneous dispersion of Al/V in the entire framework. The study of the flexibility by means of CO₂ pressure dependent XRPD and high pressure sorption reveals the co-existence of two different large pore phases and a narrow pore phase in the entire pressure regime.

This article is part of the themed collection: 2017 Journal of Materials Chemistry A HOT Papers

Download options Please wait...

Supplementary files

Supplementary information PDF (2066K)

Article information

DOI: https://doi.org/10.1039/C7TA08103K
Article type: Communication
Submitted: 14 စက် 2017
Accepted: 17 အောက် 2017
First published: 18 အောက် 2017

Download Citation

J. Mater. Chem. A, 2017,5, 24580-24584

Permissions

Request permissions

Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework

H. Depauw, I. Nevjestić, G. Wang, K. Leus, F. Callens, E. De Canck, K. De Buysser, H. Vrielinck and P. Van Der Voort, J. Mater. Chem. A, 2017, 5, 24580 DOI: 10.1039/C7TA08103K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Journal of Materials Chemistry A

Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework

Social activity

Search articles by author

Spotlight

Advertisements