Issue 1, 2010
From the journal:

Chemical Communications

Highly enantioselective hydrogenation of α-aryl-β-substituted acrylic acids catalyzed by Ir-SpinPHOX†‡

Yi Zhang,ab   Zhaobin Han,b   Fuying Li,a   Kuiling Ding*b  and  Ao Zhang*a  

* Corresponding authors

a Synthetic Organic & Medicinal Chemistry Laboratory, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, 555 Zuchongzhi Road, Shanghai 201203, P.R. China
E-mail: aozhang@mail.shcnc.ac.cn
Fax: (+86) 21 50806035

b State Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, P.R. China
E-mail: kding@mail.sioc.ac.cn
Fax: (+86) 21 64166128

Abstract

The enantioselective hydrogenation of a series of challenging substrates, α-aryl-β-substituted acrylic acids, was realized with high efficiency and enantioselectivity (up to 96%) under the catalysis of Ir(I) complex of Spiro-based P,N ligand, SpinPHOX.

Graphical abstract: Highly enantioselective hydrogenation of α-aryl-β-substituted acrylic acids catalyzed by Ir-SpinPHOX

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B919902K
Article type
Communication
Submitted
24 စက် 2009
Accepted
11 နို 2009
First published
24 နို 2009

Chem. Commun., 2010,46, 156-158

Permissions

Request permissions

Highly enantioselective hydrogenation of α-aryl-β-substituted acrylic acids catalyzed by Ir-SpinPHOX

Y. Zhang, Z. Han, F. Li, K. Ding and A. Zhang, Chem. Commun., 2010, 46, 156 DOI: 10.1039/B919902K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements