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Gelation of sulfolane-based highly concentrated electrolytes using a partially fluorinated polymer enhances the Li-ion transference number of the electrolytes because acidic protons surrounded by fluorine atoms in the polymer network trap anions, and the high Li+ transference number is effective in suppressing the concentration polarization in Li batteries.

Graphical abstract: A partially fluorinated polymer network enhances the Li-ion transference number of sulfolane-based highly concentrated electrolytes

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