Issue 45, 2023

Structural and reactive evolution of oxidatively grafted Pd catalysts on MnO2 for the low-temperature oxidation of CO

Abstract

Isolated Pd atoms supported on high surface area MnO2, prepared by the oxidative grafting of (bis(tricyclohexylphosphine-palladium(0)), catalyze (>50 turnovers, 17 h) the low temperature (≤325 K) oxidation of CO (7.7 kPa O2, 2.6 kPa CO) with results of in situ/operando and ex situ spectroscopic characterization signifying a synergistic role of Pd and MnO2 in facilitating redox turnovers.

Graphical abstract: Structural and reactive evolution of oxidatively grafted Pd catalysts on MnO2 for the low-temperature oxidation of CO

Supplementary files

Article information

Article type
Communication
Submitted
05 မတ် 2023
Accepted
10 မေ 2023
First published
11 မေ 2023

Chem. Commun., 2023,59, 6861-6864

Author version available

Structural and reactive evolution of oxidatively grafted Pd catalysts on MnO2 for the low-temperature oxidation of CO

J. N. Hall, A. J. Kropf, U. Kanbur, F. Dogan, C. Byron, J. Wen, M. Delferro and D. M. Kaphan, Chem. Commun., 2023, 59, 6861 DOI: 10.1039/D3CC01094E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements