Issue 39, 2019

CO2 activation by manganese pincer complexes through different modes of metal–ligand cooperation

Abstract

We report here the activation of CO2 using two Mn-PNN pincer complexes that can exhibit different modes of metal–ligand cooperation amido/amino mode that involves [1,2]-activation of CO2 and dearomatization/aromatization mode that involves [1,3]-activation of CO2. We also compare their catalytic activity for CO2 hydrogenation.

Graphical abstract: CO2 activation by manganese pincer complexes through different modes of metal–ligand cooperation

Supplementary files

Article information

Article type
Communication
Submitted
28 ဇူ 2019
Accepted
03 စက် 2019
First published
04 စက် 2019

Dalton Trans., 2019,48, 14580-14584

CO2 activation by manganese pincer complexes through different modes of metal–ligand cooperation

A. Kumar, P. Daw, N. A. Espinosa-Jalapa, G. Leitus, L. J. W. Shimon, Y. Ben-David and D. Milstein, Dalton Trans., 2019, 48, 14580 DOI: 10.1039/C9DT03088C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements