Issue 26, 2019

Rotational dependence of the branching ratios and fragment angular distributions for the photodissociation of 12C16O in the Rydberg 4p(2) and 5p(0) complex region (92.84–93.37 nm)

Abstract

12C16O shows complicated absorption structures in the wavelength range of 92.84–93.37 nm caused by the mutual interactions among the Rydberg 4p(2) and 5p(0) complexes, and several diffuse valence states. Here, we systematically measured the branching ratios and fragment angular distributions for the photodissociation of 12C16O in the wavelength range using our mini-time-slice velocity-map imaging (mini-TSVMI) setup and a tunable vacuum ultraviolet (VUV) laser radiation source generated by the two-photon resonance-enhanced four-wave mixing scheme. Various patterns of rotational dependence for the photodissociation branching ratios have been observed for different vibronic states, and they are found to be consistent with previous spectroscopic investigations, revealing the complicated coupling schemes and predissociation dynamics in this region. Irregular angular distributions of the photofragments have been observed, especially in the Rydberg 5p(0) complex region. This has been attributed to the simultaneous excitation of multiple states with different symmetries in this region. The newly observed underlying continuum in the Rydberg 5p(0) complex region has been directly detected in the present study, and it is found to be of 1Σ+ symmetry and dissociates predominantly into the C(3P) + O(3P) channel. This study generally confirms the results of previous spectroscopic studies from a different perspective, and adds new knowledge for understanding the complicated predissociation dynamics of 12C16O in the titled wavelength range.

Graphical abstract: Rotational dependence of the branching ratios and fragment angular distributions for the photodissociation of 12C16O in the Rydberg 4p(2) and 5p(0) complex region (92.84–93.37 nm)

Article information

Article type
Paper
Submitted
13 ဒီ 2018
Accepted
29 ဇန် 2019
First published
29 ဇန် 2019

Phys. Chem. Chem. Phys., 2019,21, 14376-14386

Rotational dependence of the branching ratios and fragment angular distributions for the photodissociation of 12C16O in the Rydberg 4p(2) and 5p(0) complex region (92.84–93.37 nm)

P. Jiang, X. Chi, W. Qi, Q. Zhu, M. Cheng and H. Gao, Phys. Chem. Chem. Phys., 2019, 21, 14376 DOI: 10.1039/C8CP07620K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements