Issue 20, 2018

The quest for high glass transition temperature bioplastics

Abstract

The field of biorenewable polymers is ever-expanding, aided by the interest of the general public to adopt more sustainable practices for natural resource utilization as well as waste generation. This review summarizes recent efforts to synthesize biobased thermoplastics with glass transition temperature (Tg) values exceeding that of polylactic acid (PLA), near 55 °C. A high Tg is essential for materials that aspire to replace any incumbent commodity plastics employed in the amorphous state. The first section focuses on commercial bioplastics and describes: approaches toward biorenewable polyethylene terephthalate (PET); efforts to improve the Tg of PLA; and advances toward polyethylene furanoate (PEF). The remaining sections catalogue a wide variety of novel, high Tg bioplastics categorized as: aromatic biopolymers, carbocyclic and heterocyclic biopolymers, and vinyl-type biopolymers synthesized via radical polymerization.

Graphical abstract: The quest for high glass transition temperature bioplastics

Article information

Article type
Review Article
Submitted
11 ဇန် 2018
Accepted
07 မတ် 2018
First published
04 ဧပြီ 2018

J. Mater. Chem. A, 2018,6, 9298-9331

Author version available

The quest for high glass transition temperature bioplastics

H. T. H. Nguyen, P. Qi, M. Rostagno, A. Feteha and S. A. Miller, J. Mater. Chem. A, 2018, 6, 9298 DOI: 10.1039/C8TA00377G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements