Issue 17, 2016

Aromatic cages B 0/+42: unprecedented existence of octagonal holes in boron clusters

Abstract

The cage-like structures containing octagonal holes are located as the lowest-lying isomers for the B0/+42. The presence of octagonal holes, which have been found for the first time, not only gives us new insight into the bonding motif, but also marks a breakthrough in the structural characteristics of boron clusters since they were never expected to be stable units for elemental clusters. These cages are composed of both delocalized σ and π electron systems that consequently make them aromatic and thermodynamically stable.

Graphical abstract: Aromatic cages B0/+42: unprecedented existence of octagonal holes in boron clusters

Associated articles

Supplementary files

Article information

Article type
Communication
Submitted
28 နို 2015
Accepted
25 ဖေ 2016
First published
29 ဖေ 2016

Phys. Chem. Chem. Phys., 2016,18, 11620-11623

Author version available

Aromatic cages B0/+42: unprecedented existence of octagonal holes in boron clusters

T. B. Tai, S. U. Lee and M. T. Nguyen, Phys. Chem. Chem. Phys., 2016, 18, 11620 DOI: 10.1039/C5CP07342A

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